Electron Microprobe Chemical Dating of Uraninite as a Reconnaissance Tool for Leucogranite Geochronology

We suggest that electron microprobe techniques may be employed to date Tertiary samples of uraninite (UO~2~), which can contain very high concentrations of radiogenic Pb after only a few million of years of U and Th decay. Although uraninite is regarded as a rare accessory mineral, it is relatively abundant in leucogranitic rocks such as those found in the Himalayan orogen. We apply the U-Th-total Pb electron microprobe chemical dating method to a uraninite crystal from a ca. 18.3 Ma dike of the Mugu granite from the Upper Mustang region of central Nepal. With this technique, we calculate a mean chemical date that is consistent with isotope-dilution thermal ionization mass spectrometry (ID-TIMS) U-Pb dates obtained from seven other uraninite grains and a monazite crystal from the same sample. Electron microprobe chemical dating yields results that typically will be an order of magnitude less precise than conventional dates: in the specific case of the Mugu granite, single point chemical dates each have ca. 1.5 Ma 2[sigma] (95%) confidence level uncertainties. However, the mean chemical date of 15 point analyses of the crystal we study has a 2SE (2 standard error) uncertainty of ca. 400 ka, comparable to uncertainties obtained with ID-TIMS. These results show that electron microprobe chemical dating of uraninite has substantial promise as a reconnaissance tool for the geochronology of young granitic rocks. The electron microprobe work also reveals substantial chemical complexity within uraninite that must be taken into account. The analyzed crystal displays a texturally and chemically distinctive core and rim that suggests episodic growth. Concentration gradients in U, Th, and Y across the boundary imply diffusive modification. We estimate the diffusivity of U, Th, and Y in uraninite at ca. 700 °C to be > 10-7 cm2 s-1. In contrast, Pb shows no distinctive concentration gradient across the core-rim boundary, implying that Pb has a much higher diffusivity in uraninite than U, Th, or Y. We estimate that Pb loss of as much as ca. 8.9% has occurred in the uraninite grains we analyzed by ID-TIMS

Tectonic evolution of the Aefjord-Sitas area, Norway-Sweden

Thesis (Ph.D.)--Massachusetts Institute of Technology, Dept. of Earth and Planetary Science, 1982.Microfiche copy available in Archives and ScienceTwo folded maps in pocket.Includes bibliographies.by Kip Vernon Hodges.Ph.D

Laser (U-Th)/He thermochronology of detrital zircons as a tool for studying surface processes in modern catchments

Author Posting. © American Geophysical Union, 2013. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Earth Surface 118 (2013): 1333–1341, doi:10.1002/jgrf.20091.Detrital mineral thermochronology of modern sediments is a valuable tool for interrogating landscape evolution. Detrital zircon (U-Th)/He thermochronology is of particular interest because zircons are durable and withstand transport in glacial and fluvial systems far better than, for example, apatite. However, because of the time-intensive nature of conventional zircon (U-Th)/He thermochronology, most previous studies of this kind have relied on data for a few tens of grains, even though conventional wisdom holds that a substantially larger number is necessary for a robust characterization of the population of cooling ages in a sample. Here, we introduce a microanalytical approach to detrital zircon (U-Th)/He thermochronology that addresses many factors that can complicate the interpretation of conventional zircon (U-Th)/He data, particularly with respect to alpha ejection and injection and U + Th zoning. In addition, this technique permits the effective dating of naturally abraded and broken grains, and, therefore, lessens the potential for sampling bias. We apply both conventional and laser microprobe techniques to a detrital sample from the Ladakh Range in the northwestern Indian Himalaya, showing that the two yield very similar principal modes of apparent ages. However, the laser microprobe data yield a broader spectrum of ages than that of the conventional data set, which we interpret to be caused by bias related to the selection requirements for zircons used for conventional dating. This method thus provides a time-efficient route to obtaining a higher-resolution distribution of dates from a single sample, which will, in turn, yield higher-fidelity constraints regarding catchment-wide erosion rates for surface process studies.Funding for this project was provided by NSF EAR-0642731, awarded to KVH and a Lewis and Clark Grant awarded to AT-L.2014-01-2

Dendritic reidite from the Chesapeake Bay impact horizon, Ocean Drilling Program Site 1073 (offshore northeastern USA): A fingerprint of distal ejecta?

High-pressure minerals provide records of processes not normally preserved in Earth’s crust. Reidite, a quenchable polymorph of zircon, forms at pressures >20 GPa during shock compression. However, there is no broad consensus among empirical, experimental, and theoretical studies on the nature of the polymorphic transformation. Here we decipher a multistage history of reidite growth recorded in a zircon grain in distal impact ejecta (offshore northeastern United States) from the ca. 35 Ma Chesapeake Bay impact event which, remarkably, experienced near-complete conversion (89%) to reidite. The grain displays two distinctive reidite habits: (1) intersecting sets of planar lamellae that are dark in cathodoluminescence (CL); and (2) dendritic epitaxial overgrowths on the lamellae that are luminescent in CL. While the former is similar to that described in literature, the latter has not been previously reported. A two-stage growth model is proposed for reidite formation at >40 GPa in Chesapeake Bay impact ejecta: formation of lamellar reidite by shearing during shock compression, followed by dendrite growth, also at high pressure, via recrystallization. The dendritic reidite is interpreted to nucleate on lamellae and replace damaged zircon adjacent to lamellae, which may be amorphous ZrSiO4 or possibly an intermediate phase, all before quenching. These results provide new insights on the microstructural evolution of the highpressure polymorphic transformation over the microseconds-long interval of reidite stability during meteorite impact. Given the formation conditions, dendritic reidite may be a unique indicator of distal ejecta

Late Cenozoic evolution of the eastern margin of the Tibetan Plateau: Inferences from ^(40)Ar/^(39)Ar and (U-Th)/He thermochronology

High topography in central Asia is perhaps the most fundamental expression of the Cenozoic Indo-Asian collision, yet an understanding of the timing and rates of development of the Tibetan Plateau remains elusive. Here we investigate the Cenozoic thermal histories of rocks along the eastern margin of the plateau adjacent to the Sichuan Basin in an effort to determine when the steep topographic escarpment that characterizes this margin developed. Temperature-time paths inferred from ^(40)Ar/^(39)Ar thermochronology of biotite, multiple diffusion domain modeling of alkali feldspar ^(40)Ar release spectra, and (U-Th)/He thermochronology of zircon and apatite imply that rocks at the present-day topographic front of the plateau underwent slow cooling (30°–50°C/m.y.) coincident with exhumation from inferred depths of ∼8–10 km, at denudation rates of 1–2 mm/yr. Samples from the interior of the plateau continued to cool relatively slowly during the same time period (∼3°C/m.y.), suggesting limited exhumation (1–2 km). However, these samples record a slight increase in cooling rate (from <1 to ∼3°C/m.y.) at some time during the middle Tertiary; the tectonic significance of this change remains uncertain. Regardless, late Cenozoic denudation in this region appears to have been markedly heterogeneous, with the highest rates of exhumation focused at the topographic front of the plateau margin. We infer that the onset of rapid cooling at the plateau margin reflects the erosional response to the development of regionally significant topographic gradients between the plateau and the stable Sichuan Basin and thus marks the onset of deformation related to the development of the Tibetan Plateau in this region. The present margin of the plateau adjacent to and north of the Sichuan Basin is apparently no older than the late Miocene or early Pliocene (∼5–12 Ma)

Музейна справа сучасної Франції на прикладі музею Бранлі

The article sums up the results of the first year of operation du quai Braniy. It also sheds light on multicultural image of modern France

Formation of the Xigaze Metamorphic Sole under Tibetan continental lithosphere reveals generic characteristics of subduction initiation

Metamorphic soles found under allochthonous oceanic lithosphere, or ophiolites, are interpreted as derived from lower plate oceanic crust material accreted to upper plate mantle during intraoceanic subduction initiation. Their metamorphic evolution is inferred to reflect the thermal structure at the site of subduction nucleation, with granulite-bearing soles linked to initiation at hot spreading centers. Here we present garnet Lu-Hf geochronology for the granulite-bearing sole of the Xigaze ophiolite in South Tibet, whose oceanic crust formed ∼130 Ma through continental forearc extension. Our study shows that sole metamorphism was ongoing by 144 Ma, implying that north-directed subduction began at least 14 million years before oceanic forearc spreading. The upper plate at the time of subduction initiation was thus continental, not oceanic. Our results demonstrate that metamorphic characteristics of soles are independent of the specific tectonic setting at the subduction nucleation site and rather provide generic constraints on the subduction initiation process

Thermochronology of the modern Indus River bedload: New insight into the controls on the marine stratigraphic record

The Indus River is the only major drainage in the western Himalaya and delivers a long geological record of continental erosion to the Arabian Sea, which may be deciphered and used to reconstruct orogenic growth if the modern bedload can be related to the mountains. In this study we collected thermochronologic data from river sediment collected near the modern delta. U-Pb ages of zircons spanning 3 Gyr show that only ∼5% of the eroding crust has been generated since India-Asia collision. The Greater Himalaya are the major source of zircons, with additional contributions from the Karakoram and Lesser Himalaya. The 39Ar/40Ar dating of muscovites gives ages that cluster between 10 and 25 Ma, differing from those recorded in the Bengal Fan. Biotite ages are generally younger, ranging 0–15 Ma. Modern average exhumation rates are estimated at ∼0.6 km/m.y. or less, and have slowed progressively since the early Miocene (∼20 Ma), although fission track (FT) dating of apatites may indicate a recent moderate acceleration in rates since the Pliocene (∼1.0 km/m.y.) driven by climate change. The 39Ar/40Ar and FT techniques emphasize the dominance of high topography in controlling the erosional flux to the ocean. Localized regions of tectonically driven, very rapid exhumation (e.g., Nanga Parbat, S. Karakoram metamorphic domes) do not dominate the erosional record